Don't Phillips Alto tubes get mercury starved, and loose their vaccum overtime, when they go EOL?
They can be hit and miss as well, some times you get a good box and they last a long time, and other times they die in a week, most of the modern stuff ain't like the older stuff was and sometimes it's not even close..
All round if your tube has a little bit of blackening just run it till it dies and enjoy it while you can, I used to look for it many years ago, now the only time I notice it, is when the light doesn't turn on but none of my florescent tubes are vintage or really special and I have lots of spares from the re-store...