Dunno the exact specs of the cfl, but very often ghey are designed to operate at significantly lower currents (so higher arc voltages), in order to cut some of the cathode fall losses off. So the F4T5 could well be significantly underdriven (the ballast is very close to a constant current source), so suffering from cathode sputtering.
Or it also possible there is nothing wrong with the setup, the observed blackening is just a condensed mercury. If this would be the case, the "blackening" should disappear once the lamp warms up completely (after about half a hour running) and appear back only when the lamp cools down (so few minutes after power down) or even only at the next stsrtup.