The part of power LEDs emit around the 450nm band exceeds that of any other light source, including all 4000...6500K discharge lighting and direct sunlight. In the working hours of the day it is not a matter of sync of the biological clock as much, but of retinal damage that would accumulate over years of exposure
It does not matter if it is exactly 450 or 480 or 420. All have the same effects and the effect is related to the sum of the power in the whole blue band. And you need to emit in the blue band if you want the high CCT, regardless of the lamp chemistry. So nothing is special to "only LED".
The LED does have everythng in a single line, but so does e.g. the MV or many MH, but it stlii plays no effect. Everything in the blue band, regardless if concentrated in one line or spread over the whole band in a continuum, has the same strong effect for the "biological clock".
And if that effect is beneficial vs detrimental to humans health depends on how the exposure to the light strong in blue is synchronized with your intended activity cycle.
Nothing from this is any new in any way, it was just not well known in the public in the past, because normal people just did not use any high CCT lights at homes, mainly around bed. The problem came only with first LEDs with very high CCT (so rich in blue), which because of being low intensity and low ciurrent consumption, were tempting to be used as nightlights. And that is the real problem. There was an attempt to notify the public about this problem, but it was worded not in a really clear way to be understood by "an ordinary Joe".
As a result it got completely misunderstood, then misinterpreted over and over and turned into the hoax about the "extremely dangerous LEDs" started spreading.
And this hoax is still being spread, even by people that should have the qualification to understand it correctly if they pay at least a bit of attention. But the laziness (instead of really verifying the basis they just repeat the misinterpretations) and fame hunger (need to be "the one to warn all the others") took over their good judgement instead.
So yes, you should be careful with where to not use daylight LEDs at home and no, it is not LEDs what makes the problem, it is the daylight (high CCT so rich in blue) light color, you should be the same way careful with any other daylight light source.